shekhawati university previous year question paper
shekhawati university previous year question paper pdf
Unit-'I'
1 Discuss perturbation theory. Derive an expression of perturbation theory to applying on Helium atom.
2. Write short notes on the following:
(i) Hamiltonian operator
(ii) Pauli's exclusion principle
(iii) Extended Huckel theory
(iv) Postulates of quantum mechanics
3. Explain fugacity. Derive an expression for determination of fugacity of a real gas. Also write any
two applications of fugacity.
msc physical chemistry notes
4 Write short notes on the following:(1 Second order phase transitions
( 2) Lagrange's method of undetermined multipliers
(3 ) Vibrational partition function
(4 ) Onsagar's reciprocity relations
Unit-'III
msc physical chemistry notes pdf
(a) Derive an rate expression for H, and Brz photochemical reaction.
(b) Discuss kinetic and thermodynamic control of reaction.
Write short notes on any two of the following:
1 Primary kinetic salt effect
2 Kinetics of pyrolysis of acetaldehyde
3 Lindemann theory
7. Write short notes on the following:
1 Kelvin equation
2 Electro-Kinetic phenomenon
3 Phase separation model of micellization
(iv) Reverse micelles
8. (a) Write the kinetics of polymerisation.
(b) Discuss osmometry and viscometry method f molecular mass determination.
shekhawati university previous year question paper pdf
9 Write short notes on any two of the following:(i) Stern Model of electrified interface
(ii) Effect of light at semiconductor solution interface
(iii) Debye Huckel Jerum Mode.
10. (a) Derive an expression for Butler-Volmer equation.
(b) Discuss instrumentation and theory of polarography
